Publications
2019
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Chandrasekhar, V; Chakraborty, A.“Phosphazenes.”In “Organophosphorus Chemistry” Volume 48, Eds. David W. Allen, David Loakes and John C. Tebby. Royal Society of Chemistry, Cambridge, U. K. 2019, 400-423.
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Dey, A.; Das, S.; Mereacre, V.; Powell, A. K.; Chandrasekhar, V.“ Butterfly-shaped, heterometallic, hexanuclear, [FeIII2LnIII4] (LnIII = GdIII, TbIII, DyIII and HoIII) complexes: syntheses, structure and magnetism.”Inorg. Chim. Acta. 2019, 486, 458-467 (R. N. Mukherjee Issue)
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Kalita, P.; Goura, J.; Martinez, J. M. H.; Colacio, E.; Chandrasekhar, V.“ Homodinuclear {LnIII2} (LnIII = GdIII, TbIII, HoIII, and DyIII) complexes: field-induced SMM behavior of the DyIII and TbIII analogues.”Eur. J. Inorg. Chem. 2019, 212-220.
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Santra, B.; Mandal, D.; Gupta, V.; Kalita, P.; Kumar, V.; Narayanan, R. S.; Dey, A.; Chrysochos, N.; Mohammad, A.; Singh, A.; Zimmer, M.; Dalapati, R.; Biswas, S.; Schulzke, Carola.; Chandrasekhar, V.; Scheschkewitz, D.; Jana, A.“ Structural diversity in supramolecular organization of anionic phosphate monoesters: role of cations.”ACS Omega 2019, 4, 2118-2133.
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Pandey, M. D.; Metre, R. K.; Kundu, S.; Mahanti, B.; Kumar, A.; Gopal, K.; Chandrasekhar, V.“Luminescent pyrene-decorated organotin compounds: observation of monomer and excimer emission.”Cryst. Growth & Des. 2019, 19, 1888-1895.
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Chakraborty, A.; Goura, J.; Bag, P.; Chandrasekhar, V.“ NiII-LnIII Heterometallic complexes as single-molecule magnets.”Eur. J. Inorg. Chem. 2019, 1180-1200.
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Mandal, D.; Sobottka, S.; Dolai, R.; Maiti, A.; Dhara, D.; Kalita, P.; Narayanan, R. S.; Chandrasekhar, V.; Sarkar, B.; Jana, A.“Direct access to 2-aryl substituted pyrrolinium salts for carbon centre based radicals without pyrrolidine-2-ylidene alias cyclic(alkyl)(amino)carbene (CAAC) as a precursor.”Chem. Sci. 2019, 10, 4077-4081.
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Kalita, P.; Malakar, A.; Goura, J.; Nayak, S.; Herrera, J. M.; Colacio, E.; Chandrasekhar, V.“Mononuclear lanthanide complexes assembled from a tridentate NNO donor ligand: design of a DyIII single-ion magnet.”Dalton Trans. 2019, 48, 4857-4866.
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Biswas, S.; Kumar, P.; Swain, A.; Gupta, T.; Kalita, P.; Kundu, S.; Rajaraman, G.; Chandrasekhar, V.“ Phosphonate-assisted tetranuclear lanthanide assemblies: observation of the toroidic ground state in the TbIII analogue.”Dalton Trans. 2019, 48, 6421-6434.
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Kundu, S; Sinhababu, S; Chandrasekhar, V; Roesky, H. W.“ Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents. ”Chem. Sci. 2019, 10, 4727-4741.
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Chandrasekhar, V.; Jin, G.-X.; Low, P. J.“ New talent: Asia-Pacific. ”Dalton Trans. 2019, 48, 7046-7046.
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Santra, B.; Narayanan, R. S.; Kalita, P.; Kumar, V.; Mandal, D.; Gupta, V.; Zimmer, M.; Huch, V.;Chandrasekhar, V.; Scheschkewitz, D.; Schulzke, C.; Jana, A.“ Modulation of the nuclearity of molecular Mg(II)-phosphates: solid-state structural change involving coordinating solvents.”Dalton Trans. 2019, …
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2018
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Chandrasekhar, V.; Narayanan, R.S.; Mamidala, R.; Venkatasubbaiah, K.“Phosphazenes.”In “Organophosphorus Chemistry” Volume 47, Eds. David W. Allen, David Loakes and John C. Tebby. Royal Society of Chemistry, Cambridge, U. K. 2018, 363-424.
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Bar, A. K.; Kalita, P.; Sutter, J.-P.; Chandrasekhar, V.“Pentagonal-bipyramid Ln(III) complexes exhibiting single-ion magnet behavior: a rational synthetic approach for a rigid equatorial plane.”Inorg. Chem. 2018, 57, 2398-2401.
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Chandrasekhar, V.; Mahanti, B.; Pandey, M. D.; Narayanan, R. S.“Cyclometalated Ir(III) complex as a metalloligand and a selective Cu(II) sensor: synthesis and structural characterization of a heterometallic tetranuclear Ir(III)/Cu(II) complex.”ACS Omega, 2018, 3, 2786-2792.
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Dey, A.; Das, S.; Palacios, M. A.; Colacio, E.; Chandrasekhar, V.“Single-molecule magnet and magnetothermal properties of two dimensional polymers containing heterometallic [Cu5Ln2] (Ln = GdIII and DyIII) motifs.”Eur. J. Inorg. Chem. 2018, 1645-54.
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Dhara, D.; Kalita, P.; Mondal, S.; Narayanan, R. S.; Mote, K. R.; Huch, V.; Zimmer, M.; Yildiz, C. B.; Scheschkewitz, D.; Chandrasekhar, V.; Jana, A.“Reactivity enhancement of a diphosphene by reversible N-heterocyclic carbene coordination.”Chem. Sci. 2018, 9, 4235-43.
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Singh, A. S.; Ali, A.; Behera, J. N.; Sun, S.-S.; Chandrasekhar, V.; Tiwari, R. K.“Thermal induced 1D to 2D polymer conversion accompanied by major packing changes in a single-crystal- to-single-crystal transformation.”CrystEngCommun. 2018, 20, 2346-50.
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Bar, A. K.; Kalita, P.; Singh, M. K.; Rajaraman, G.; Chandrasekhar, V.“ Low-coordinate mononuclear lanthanide complexes as molecular nanomagnets.”Coord. Chem. Rev. 2018, 367, 163-216.
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Kalita, P.; Goura, J.; Herrera, J. M.; Colacio, E.; Chandrasekhar, V.“Heterometallic octanuclear NiII4LnIII4(Ln = Gd, Tb, Dy, Ho, Er) complexes containing NiII2LnIII2O4 distorted cubane motifs: synthesis, structure and magnetic properties.”ACS Omega, 2018, 3, 5202-11.
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Dey, A.; Kalita, P.; Chandrasekhar, V.“ Lanthanide(III)-based single-ion magnets.”ACS Omega, 2018, 3, 9462-9475.
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Mandal, D.; Dolai, R.; Kalita, P.; Naraynan, R. S.; Kumar, R.; Sobottka, S.; Sarkar, B.; Rajaraman, G.; Chandrasekhar, V.; Jana, A.“ “Abnormal” addition of NHC to a conjugate acid of CAAC: formation of N-alkyl-substituted CAAC. ”Chem. Eur. J. 2018, 24, 12722-727.
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Narayanan, R. S.; Thilagar, P.; Acharya, J.; Kumar, P.; Rao, D. K.; Chandrasekhar, V.; Jana, A.“Reactions of 4-diphenylphosphinobenzoic acid with organotin oxides and oxy-hydroxide. ”J. Chem. Sci. 2018, 130, 1-8.
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Chakraborty, A.; Goura, J.; Kalita, P.; Swain, A.; Rajaraman, G.; Chandrasekhar, V.“Heterometallic 3d-4f single molecule magnets containing diamagnetic metal ions.”Dalton. Trans. 2018, 47, 8841-64.
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Acharya, J.; Biswas, S.; van Leusen, J.; Kumar, P.; Vierendra.; Narayanan, R. S.; Kögerler, P.; Chandrasekhar, V.“Exploring tuning of structural and magnetic properties of modification of ancillary β-diketonate co-ligands in a family of near-linear tetranuclear Dy(III) complexes.”Cryst. Growth. Des. 2018, 18, 4004-16.
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Dhara, D.; Vijayakanth, T.; Nayak, M. K.; Kalita, P.; Boomishankar, R.; Yildiz, C. B.; Chandrasekhar, V.; Jana, A.“Contrasting reactivity of (boryl)(aryl)lithium-amide with electrophiles: N- vs. p-aryl-C-nucleophilic substitution.”Dalton. Trans. 2018, 47, 14411-15.
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Gupta, V.; Santra, B.; Mandal, D.; Das, S.; Narayanan, R. S.; Kalita, P.; Rao, D. K.; Schulzke, C.; Pati, S. K.; Chandrasekhar, V.; Jana, A.“ Neutral and anionic phosphate-diesters as molecular templates for the encapsulation of a water dimer.”Chem. Commun. 2018, 54, 11913-16.
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2017
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Chandrasekhar, V.; Narayanan, R. S.“Phosphazenes.”In “Organophosphorus Chemistry” Volume 46, Eds. David W. Allen, David Loakes and John C. Tebby. Royal Society of Chemistry, Cambridge, U. K. 2017, 342-417.
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Singh, A. S.; Tiwari, R. K.; Lee, M. M.; Behera, J. N.; Sun, S-S.; Chandrasekhar, V.“Structural tuning of anion-templated motifs with external stimuli through crystal-to-crystal transformation.”Chem. A. Eur. J. 2017, 23, 762-766.
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Biswas, S.; Bag, P.; Das, S.; Kundu, S.; van Leusen, J.; Kögerler, P.; Chandrasekhar, V.“Heterometallic [Cu2Ln3] (Ln = Dy(III), Gd(III) and Ho(III)) and [Cu4Ln2] (Ln = Dy(III) and Ho(III)) compounds: synthesis, structure and magnetism.”Eur. J. Inorg. Chem. 2017, 1129-1142.
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Biswas, S.; Das, S.; Acharya, J.; Kumar, V.; van Leusen, J.; Kögerler, P.; Herrera, J. M.; Colacio, E.; Chandrasekhar, V.“Homometallic DyIII Complexes of varying nuclearity from 2 to 21: synthesis, structure and magnetism.”Chem. Eur. J. 2017, 23, 5154-5170.
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Biswas, S.; Bejoymohandas, K. S.; Das, S.; Kalita, P.; Reddy, M. L. P.; Oyarzabal, I.; Colacio, E.; Chandrasekhar, V.“Mononuclear lanthanide complexes: energy-barrier enhancement by ligand substitution in field-induced Dy(III) SIMs.”Inorg. Chem. 2017, 56, 7985-7997.
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Dhara, D.; Vijayakanth, T.; Barman, M. K.; Naik, K. P. K.; Chrysochos, N.; Yildiz, C. B.; Boomishankar, R.; Schulzke, C.; Chandrasekhar, V.; Jana, A.“NHC-stabilized 1-hydrosilaimine: synthesis, structure and reactivity.”Chem. Commun. 2017, 53, 8592-8595.
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Mandal, D.; Santra, B.; Kalita, P.; Chrysochos, N.; Malakar, A.; Narayanan, R. S.; Biswas, S.; Schulzke, C.; Chandrasekhar, V.; Jana, A.“2,6-(Diphenylmethyl)-aryl-substituted neutral and anionic phosphates: approaches to H-bonded dimeric molecular structures.”Chem. Select 2017, 2, 8898-8910.
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Mandal, D.; Dolai, R.; Chrysochos, N.; Kalita, P.; Kumar, R.; Dhara, D.; Maiti, A.; Narayanan, R. S.; Rajaraman, G.; Schulzke, C.; Chandrasekhar,V.; Jana, A.“Stepwise reversible oxidation of N-peralkyl-substituted NHC-CAAC derived triazaalkenes: isolation of radical cations and dications.”Org. Lett. 2017, 19, 5605-5608.
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“Heterometallic Zn3Ln3 ensembles containing (µ6-CO3) ligand and triangular disposition of Ln3+ions: analysis of single-molecule toroic (SMT) and single-molecule magnet (SMM) behavior.”Chem. Eur. J. 2017, 23, 16621-16636.
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Dey, A.; Das, S.; Kundu, S.; Mondal, A.; Rouzieres, M.; Mathoniere, C.; Clérac, R.; Narayanan, R. S.; Chandrasekhar, V.“Heterometallic heptanuclear [Cu5Ln2] (Ln = Tb, Dy, and Ho) single-molecule magnets organized in one-dimensional coordination polymeric network.”Inorg. Chem. 2017, 56, 14612-14623
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2016
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Chandrasekhar, V.; Narayanan, R. S.“Phosphazenes.”In “Organophosphorus Chemistry” Volume 45, Eds. David W. Allen, David Loakes and John C. Tebby. Royal Society of Chemistry, Cambridge, U. K. 2016, 375-433.
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Narayanan, R. S.; Chandrasekhar, V.“Molecular, 1D and 2D assemblies from hexakis(3-pyridyloxy)cyclophosphazene containing 20-membered metallamacrocyclic motifs.”Dalton Trans. 2016, 45, 2273-2283.
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Goura, J.; Brambleby, J.; Topping, C. V.; Goddard, P. A.; Narayanan, R. S.; Bar, A. K.; Chandrasekhar, V.“Heterometallic trinuclear {Co(III)2Ln(III)} (Ln = Gd, Tb, Ho and Er) complexes in a bent geometry. Field-induced single-ion magnetic behavior of the Er(III) and Tb(III) analogues.”Dalton Trans. 2016, 45, 9235-9249.
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Kundu, S.; Nagapradeep, N.; Mohapatra, B.; Biswas, S.; Verma, S.; Chandrasekhar, V.“Organostannoxane-supported nucleobase arrays: synthesis and supramolecular structures of polymeric and molecular organotin complexes containing guanine, uracil and 2-aminopurine.”Cryst. Eng. Commun. 2016, 18, 4807-4817.
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Chakraborty, A.; Goura, J.; Bag, P.; Bar, A. K.; Sutter, J.-P.; Chandrasekhar, V.“Windmill-shaped octanuclear ZnII4/LnIII4 (LnIII = Dy, Tb, Ho) heterometallic ensembles supported by a tetraferrocene scaffold.”Dalton. Trans. 2016, 45, 17633-17643.
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Dhara, D.; Mandal, D.; Maiti, A.; Yildiz, C. B.; Cem, B.; Kalita, P.; Chrysochos, N.; Schulzke, C.; Chandrasekhar, V.; Jana, A.“Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(IV) precursors: a Lewis acid-base complex.”Dalton Trans. 2016, 45, 19290-19298.
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Biswas, S.; Das, S.; Rogez, G.; Chandrasekhar, V.“Hydrazone-ligand-based homodinuclear lanthanide complexes: synthesis, structure, and magnetism.”Eur. J. Inorg. Chem. 2016, 3322-3329.
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Biswas, S.; Das, S.; Hossain, S.; Bar, A. K.; Sutter, J.-P.; Chandrasekhar, V.“Tetranuclear lanthanide(III) complexes containing a square-grid core: synthesis, structure, and magnetism.”Eur. J. Inorg. Chem. 2016, 4683-4692.
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Biswas, S.; Goura, J.; Das, S.; Topping, C. V.; Brambleby, J.; Goddard, P. A.; Chandrasekhar, V.“Octanuclear heterobimetallic {Ni4Ln4} assemblies possessing Ln4 Square Grid [2 × 2] motifs: synthesis, structure, and magnetism.”Inorg. Chem. 2016, 55, 8422-8436.
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Chandrasekhar, V.; Narayanan, R. S..“Organostannoxanes containing peripheral thiomethyl groups.”Proc. Nat. Acad. Sci. A. 2016, 86, 627-632.
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Biswas, S.; Das, S.; Gupta, T.; Singh, S. K.; Pissas, M.; Rajaraman, G.; Chandrasekhar, V.“Observation of Slow Relaxation and Single-Molecule Toroidal Behavior in a Family of Butterfly-Shaped Ln4 Complexes.”Chem. A. Eur. J. 2016, 22, 18532-18550.
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2015
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Goura, J.; Brambleby, J.; Goddard, P.; Chandrasekhar, V. “A single-ion magnet based on a heterometallic CoIII2 Dy III complex. ”,Chem. Eur. J. 2015, 21, 4926-4930
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Goura, J.; Walsh, J. P. S.; Tuna, F.; Chandrasekhar, V. “Synthesis, structure, and magnetism of non-planar heptanuclear lanthanide(III) complexes. ”,Dalton Trans. 2015, 44, 1142-1149.
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Goura, J.; Mereacre, V.; Novitchi, G.; Powell, A. K.; Chandrasekhar, V. “Homometallic FeIII4 and heterometallic {FeIII4LnIII2}(Ln = Dy, Tb) complexes: synthesis, structure and magnetism. ”Eur. J. Inorg. Chem. 2015, 156-165.
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Kundu, S.; Mohapatra, B.; Mohapatra, C.; Verma, S.; Chandrasekhar, V. “Polymeric, molecular and ionic organotin complexes containing hypoxanthine, adenine and 2-aminopurine. Synthesis and supramolecular structures. ”Cryst. Growth Des. 2015, 15, 247-256.
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Bag, P.; Rastogi, C. K.; Biswas, S.; Sivakumar, S.; Mereacre, V.; Chandrasekhar, V. “Homodinuclear lanthanide {Ln2} (Ln = Gd, Tb, Dy, Eu) complexes prepared from an o-vanillin based ligand: luminescence and single-molecule magnetism behavior. ”Dalton Trans. 2015, 44, 4328-4340.
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Biswas, S.; Das, S.; van Leusen, J.; Kӧgerler, P.; Chandrasekhar, V. “ Pentanuclear [2.2] spirocyclic lanthanide(III) complexes: slow magnetic relaxation of Dy(III) analogue. ”Dalton Trans. 2015, 44, 19282-19293.
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Chakraborty, A.; Bag, P.; Goura, J.; Bar, A. K.; Sutter, J-P.; Chandrasekhar, V.“Chair-shaped MnII2LnIII4 (Ln = Gd, Tb, Dy, Ho) heterometallic complexes assembled from a tri-compartmental aminobenzohydrazide ligand.”Cryst. Growth Des. 2015, 15, 848-857.
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Das, S.; Bejoymohandas, K. S.; Dey, A.; Biswas, S.; Reddy, M. L. P.; Morales, R.; Ruiz, E.; Titos-Padilla, S.; Colacio, E.; Chandrasekhar, V.“Amending the anisotropy barrier and luminescence behavior of heterometallic trinuclear linear [MII-LnIII-MII] (LnIII = Gd, Tb, Dy; MII = Mg/Zn) complexes by change from divalent paramagnetic to diamagnetic metal ions.”Chem. Eur. J. 2015, 21, 6449-6464.
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Goura, J.; Walsh, J. P. S.; Tuna, F.; Halder, R.; Maji, T. K.; Chandrasekhar, V.“P-C Bond cleavage-assisted lanthanide phosphate coordination polymers.”Cryst. Growth Des. 2015, 15, 2555–2560.
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Goura, J.; Chakraborty, A.; Walsh, J. P. S.; Tuna, F.; Chandrasekhar, V.“Hexanuclear 3d-4f neutral CoII2LnIII4 clusters: synthesis, structure and magnetism.”Cryst. Growth Des. 2015, 15, 3157–3165.
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Goura, J.; Chandrasekhar, V.“Molecular metal phosphonates.”Chem. Rev. 2015, 115, 6854–6965.
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Kundu, S.; Chandrasekhar, V.“ η6-Benzene(tricarbonyl) chromium and cymantrene assemblies supported on an organostannoxane platform.”Cryst. Growth. Des. 2015, 11, 5437-5450.
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Das, S.; Dey, A.; Kundu, S.; Biswas, S.; Narayanan, R. S.; Titos, S. P.; Lorusso, G.; Evangelisti, M.; Colacio, E.; Chandrasekhar, V.“Decanuclear Ln10 wheels and vertex-shared spirocyclic Ln5 cores: synthesis, structure, SMM and MCE properties.”Chem. Eur. J. 2015, 21, 16955-16967.
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Goura, J.; Oyarzabal, I.; Colacio, E.; Chandrasekhar, V.“Synthesis, structure and magnetic properties of phosphinate-bridged hexanuclear FeIII complexes containing two butterfly-shaped Fe3O cores.”Eur. J. Inorg. Chem. 2015, 34, 5601-5610.
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Metre, R. K.; Kundu, S.; Narayanan, R. S.; Chandrasekhar, V.“Bismuth phosphinates: temperature-dependent formation of a macrocycle and 1D coordination polymer.”Phosphorus, Sulfur, Silicon and Related Elements 2015, 190, 2134-2141. (Special Issue Dedicated to Prof. R. R. Holmes).
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2014
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S. Das, A. Dey, S. Biswas, E. Colacio, V. Chandrasekhar, "Hydroxide-Free Cubane-Shaped Tetranuclear [Ln4] Complexes", Inorg. Chem. 2014, 53, 3417-3426.
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V.Chandreshekar, J.Goura, K.Gopal, J.Liu, P.Goddard,
"Synthesis, Structure and Magnetism of the Mixed-Valent Phosphonate Cage, [MnII MnIII12(µ4-O)(µ-OH)6(O3P-t-Bu)10(OH2)2(DMF)4][2MeOH 4DMF]", Polyhedron 2014,72,35-42. -
S. Kundu, R. K. Metre, R. Yadav, P. Sen, V. Chandrasekhar,"Multi-Pyrene Assemblies Supported on Stannoxane Frameworks: Synthesis, Structure and Photophysical Studies",Chem. Asian J. 2014, Ahead of Print
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J. Goura, J. P. S. Walsh, F. Tuna, V. Chandrasekhar,
"Tetranuclear Lanthanide(III) Complexes in a Seesaw Geometry: Synthesis, Structure, and Magnetism", Inorg. Chem. 2014, 53, 3385-3391. -
K. Gopal, S. Kundu, R. K. Metre, V. Chandrasekhar, "Ambient Temperature Sn-C Bond Cleavage Reaction Involving the Sn-n-butyl Group. Weak F���F Interactions in the Solid State Structure of [{nBu2SnO2C-C6H4-4-CF3}2O2",Z. Anorg. Allg. 2014, Ahead of Print.
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R. K. Metre, C. Mohapatra, D. Sahoo, V. Chandrasekhar, "Assembly of Hexa- and Trinuclear Monoorganostannoxanes: Hemi-Labile Nature of Intramolecular N → Sn Coordination in RSnCl3 (R = 2-phenylazophenyl)", Dalton Trans. 2014, 43, 3364-3371.
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V. Chandrasekhar, A. Dey, S. Das, S. Kundu, "Syntheses and Structures of a Family Of Heterometallic Pentanuclear [MnIII3LnNa] (Ln = Dy, Tb, Gd and Nd) Complexes: H-Bonding Reduces the Nuclearity from Nine to Five", CrystEngComm. 2014, 16, 1304-1310.
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C. Mohapatra, V. Chandrasekhar, "Two-Dimensional Homometallic- to a Three Dimensional Heterometallic Coordination Polymer: A Metalloligand Approach", Cryst. Growth Des. 2014, 14, 406-409.
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S. Kundu, A. Chakraborty, K. Mondal, V. Chandrasekhar, "Multi-Ruthenocene Assemblies on an Organostannoxane Platform. Supramolecular Signatures and Conversion to (Ru-Sn)O2", Cryst. Growth Des. 2014, 14, 861-870.
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V. Chandrasekhar, S. Das, A. Dey, S. Hossain, S. Kundu, E. Colacio, "Linear, Edge-Sharing Heterometallic Trinuclear [CoII-LnIII-CoII| (LnIII = GdIII, DyIII, TbIII, and HoIII) Complexes: Slow Relaxation of Magnetization in the DyIII Derivative", Eur. J. Inorg. Chem. 2014, 397-406.
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V. Chandrasekhar, R. K. Metre, D. Sahoo, "Bi38 Oxocarboxylate Cages are Keplerates - Synthesis and Structural Characterization of Two Bi38 Oxocarboxylate Cages", Eur. J. Inorg. Chem. 2014, 164-171.
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S. Das, A. Dey, S. Kundu, S. Biswas, A. J. Mota, E. Colacio, V. Chandrasekhar, "Linear {NiII-LnIII-NiII} Complexes Containing Twisted Planar Ni(µ-phenolate)2Ln Fragments: Synthesis, Structure, and Magnetothermal Properties", Chem. Asian J. 2014, Ahead of Print.
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R. K. Metre, S. Kundu, D. Sahoo, V. Chandrasekhar, "Reactions of RTeCl3 (R = 2-phenylazophenyl) with Diorganophosphinic Acids. Te-C Bond Cleavage and Stabilization of the Te:O Motif in an Umbrella-Shaped Te5O11P2 Multi-metallacyclic Framework", Organometallics 2014, 33, 2380-2383.
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D. Sahoo, R. Suriyanarayanan, V. Chandrasekhar, "A 30-Membered Nonanuclear Cobalt(II) Macrocycle Containing Phosphonate-Bridged Trinuclear Subunits", Cryst. Growth Des. 2014, Ahead of Print.
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S. Das, S. Hossain, A. Dey, S. Biswas, J. P. Sutter, V. Chandrasekhar, "Molecular Magnets Based on Homometallic Hexanuclear Lanthanide(III) Complexes", Inorg. Chem. 2014, 53, 5020-5028.
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V. Chandrasekhar, B. Mahanti, "A Cyclometalated Ir(III) Complex Containing N-naphthyl Picolinamide Ancillary Ligand", Proc. Nat. Acad. Sci. India, Section A: Physical Sciences 2014, 84, 115-120.
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D. Sahoo, R. K. Metre, W. Kroener, K. Gieb, P. Mueller, V. Chandrasekhar, "A Planar Decanuclear Cobalt(II) Phosphonate
", Eur. J. Inorg. Chem. 2014, 2490-2494. -
D. Sahoo, R. Suriyanarayanan, R. K. Metre, V. Chandrasekhar, "Molecular and Polymeric Zinc(II) Phosphonates: Isolation of an Octanuclear Ellipsoidal Ensemble", Dalton Trans. 2014, 43, 7304-7313.
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A. Chakraborty, P. Bag, E. Rivi�re, T. Mallah, V. Chandrasekhar, "Assembly of Heterobimetallic NiII�LnIII (LnIII = DyIII, TbIII, GdIII, HoIII, ErIII, YIII) Complexes Using a Ferrocene Ligand: Slow Relaxation of the Magnetization in DyIII, TbIII and HoIII Analogues", Dalton Trans. 2014, 43, 8921-8932.
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V. Chandrasekhar, S. Hossain, S. Das, A. Chakraborty, E. Pardo, J. Cano, F. Lloret, "S-Shaped Decanuclear Heterometallic [Ni8Ln2] Complexes [Ln(III) = Gd, Tb, Dy and Ho]: Theoretical Modeling of the Magnetic Properties of the Gadolinium Analogue", Dalton Trans. 2014, 43, 10164-10174.
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J. Goura, P. Bag, V. Mereacre, A.K. Powell, V. Chandrasekhar, "Molecular Iron(III) Phosphonates: Synthesis, Structure, Magnetism, and Mossbauer Studies", Inorg. Chem. 2014, 53, 8147-8154.
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J. Goura, J. Liu, P. Goddard, V. Chandrasekhar, "A Direct Three-Component Reaction for the Isolation of a Nonanuclear Iron(III) Phosphonate", Eur. J. Inorg. Chem. 2014, Ahead of Print.
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P. Bag, A. Chakraborty, M. Rouzieres, R. Clerac, R. J. Butcher, V. Chandrasekhar, "Oxalato- bridged Neutral Octanuclear Heterometallic Complexes [Ln4K4(L)4(µ-H2O)4(NO3)2(µ-Ox)] (Ln = Dy(III), Gd(III), Tb(III), Ho(III); LH3 = N[CH2CH2N=CH-C6H3-2-OH-3-OMe]3; Ox = (C2O4)2-): Synthesis, Structure, Magnetism and Photophysical Properties", Cryst. Growth Des. 2014, Ahead of Print.
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J. Goura, R. Guillaume, E. Riviere, V. Chandrasekhar, "Hexanuclear, Heterometallic, Ni3Ln3 Complexes Possessing O-Capped Homo- and Heterometallic Structural Subunits: SMM Behavior of the Dysprosium Analogue", Inorg. Chem. 2014, 53, 7815-7823.
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S. Biswas, S. Das, J. van Leusen, P. Koegerler, V. Chandrasekhar,"Tetranuclear [2�2] Square-Grid Lanthanide(III) Complexes: Syntheses, Structures, and Magnetic Properties", Eur. J. Inorg. Chem. 2014, Ahead of Print.
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D. Sahoo, R. Suriyanarayanan, V. Chandrasekhar"Di-, tri- and tetranuclear molecular vanadium phosphonates: a chloride encapsulated tetranuclear bowl", Dalton Trans. 2014, 43, 10898-10909.
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S. Das, S. Hossain, A. Dey, Atanu; S. Biswas, E. Pardo, F. Lloret, V. Chandrasekhar,"Heterometallic Pentanuclear [Ni4Ln] (LnIII = Gd, Tb, Dy, Ho) Complexes: Accidental Orthogonality Leading to Ferromagnetic Interaction", Eur. J. Inorg. Chem. 2014, 3393-3400.
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C. Mohapatra, S. Tripathi, G. Anantharaman, V. Chandrasekhar,
"A Hexameric Hexagonal Organotin Macrocycle. Supramolecular Entrapment of an Iodide-Iodide Short Contact", Cryst. Growth Des. 2014, 14, 3182-3185. -
P. Bag, A. Chakraborty, G. Rogez,V.Chandrasekhar,"Pentanuclear Heterometallic {MnIII2Ln3} (Ln = Gd, Dy, Tb, Ho) Assemblies in an Open-Book Type Structural Topology: Appearance of Slow Relaxation of Magnetization in the Dy(III) and Ho(III) Analogues", Inorg. Chem. 2014, 53, 6524-6533.
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S. Kundu, C. Mohapatra, V. Chandrasekhar,"Cyclophosphazene-organostannoxane hybrid motifs in polymeric and molecular systems", RSC Advances (2014), 4(96), 53662-53664.
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J. Goura, Joydeb; J. P. S. Walsh, F. Tuna, V.Chandrasekhar," Synthesis, Structure, and Magnetism of Non-planar Heptanuclear Lanthanide(III) Complexes", Dalton Transactions (2014), DOI:10.1039/C4DT01603C.
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2013
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V. Chandrasekhar, R. Suriya Narayanan, "Pyridyloxy cyclophosphazenes and carbophosphazenes: Inorganic ring-supported coordination platforms", Chimia. 2013, 67, 64-70.
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V. Chandrasekhar, R. Suriya Narayanan, "Metalation studies of 3-and 4-pyridyloxycyclophosphazenes: metallamacrocycles to coordination polymers", Dalton Trans. 2013, 6619-6632.
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V. Chandrasekhar, R. K. Metre, R. Suriya Narayanan, "Lipophilic bismuth phosphates: a molecular tetradecanuclear cage and a 1D-coordination polymer. Synthesis, structure and conversion to BiPO4", Dalton Trans. 2013, 8709-8716.
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V. Chandrasekhar, D. Sahoo, R. Suriya Narayanan, R.J. Butcher, F. Lloret, E. Pardo, "A Hexaicosametallic Copper(II) Phosphonate", Dalton Trans. 2013, 42, 8192-8196.
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V. Chandrasekhar, A. Chakraborty, E. C. Sanudo, "Ferrocene-based compartmental ligand for the assembly of neutral Zn(II)/Ln(III) heterometallic complexes", Dalton Trans. 2013, 42, 13436-13443.
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V. Chandrasekhar, D. Sahoo, R. K. Metre, "Isomorphic Co(II) and Zn(II) phosphonates: co-crystal formation of [{M2(η1-DMPzH)4(Cl3CPO3)2}{M(η1-DMPzH)2Cl2}2](toluene)2 (M = Co(II) and Zn(II))", CrystEngCommun. 2013, 15, 7419-7422.
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V. Chandrasekhar, P. Bag, B. Murugesapandian, A phosphorus-based compartmental ligand, (S)P[N(Me)N=CH-C6H3-2-O-3-OMe]3 (LH3), enables the assembly of luminescent heterobimetallic linear {L2Zn2Ln}+ [ Ln = Gd, Tb, Nd and Eu] complexes, Dalton Trans. 2013, 42, 15447-15456.
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V. Chandrasekhar, A. Dey, S. Das, M. Rouzi�res, R. Clérac, "Syntheses, structures, and magnetic properties of a family of heterometallic heptanuclear [Cu5Ln2] (Ln = Y(III), Lu(III), Dy(III), Ho(III), Er(III), and Yb(III)) complexes: Observation of SMM behavior for the Dy(III) and Ho(III) analogues", Inorg. Chem. 2013, 52, 2588-2598.
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V. Chandrasekhar, A. Kumar, M. D. Pandey, R. K. Metre, "Telluroxane-supported coordination ligands: Synthetic and structural aspects", Polyhedron (Special Alfred Werner Issue) 2013, 52, 1362-1368.
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V. Chandrasekhar, C. Mohapatra, R. Banerjee, A. Mallick, "Synthesis, structure, and H2/CO2 adsorption in a three-dimensional 4-connected triorganotin coordination polymer with a sqc topology", Inorg. Chem. 2013, 52, 3579-3581.
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V. Chandrasekhar, S. Kundu, J. Kumar, S. Verma, K. Gopal, A. Chaturbedi, K. Subramaniam, "Supramolecular signatures of adenine-containing organostannoxane assemblies", Cryst. Growth Des. 2013, 13, 1665-1675.
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O. Reu, A. Palii, S. Ostrovsky, W. Wallace, O. Zaharko, V. Chandrasekhar, R. Clerac, S. Klokishner, "Experimental characterization and theoretical modeling of a linear [CoII2TbIII] single molecule magnet", J. Phy. Chem. C 2013, 117, 6880-6888.
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V. Chandrasekhar, P. Bag, E. Colacio, "Octanuclear {LnIII8}(Ln = Gd, Tb, Dy, Ho) macrocyclic complexes in a cyclooctadiene-like conformation: Manifestation of slow relaxation of magnetization in the Dy(III) derivative", Inorg. Chem. 2013, 52, 4562-4570.
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V. Chandrasekhar, A. Dey, A. J. Mota, E. Colacio, "Slow magnetic relaxation in Co(III)-Co(II) mixed-valence dinuclear complexes with a CoIIO5X (X = Cl, Br, NO3) distorted-octahedral coordination sphere", Inorg. Chem. 2013, 52, 4554-61.
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V. Chandrasekhar, P. Bag, M. Speldrich, J. Van Leusen, P. K�gerler, "Synthesis, structure, and magnetic properties of a new family of tetra-nuclear {Mn2IIILn2}(Ln = Dy, Gd, Tb, Ho) clusters with an arch-type topology: Single-molecule magnetism behavior in the dysprosium and terbium analogues", Inorg. Chem. 2013, 52, 5035-5044.
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V. Chandrasekhar, J. Goura, A. Duthie, "Molecular indium(III) phosphonates possessing ring and cage structures. synthesis and structural characterization of [In2(t -BuPO3H)4(phen)2Cl2] and [In3(C5H9PO3)2(C5H9PO3H)4(phen)3]�NO3�3.5H2O", Inorg. Chem. 2013, 52, 4819-4824.
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V. Chandrasekhar, S. Hossain, S. Das, S. Biswas, J. P. Sutter, "Rhombus-Shaped Tetranuclear [Ln4] Complexes [Ln = Dy(III) and Ho(III)]: Synthesis, Structure, and SMM Behavior", Inorg. Chem. 2013, 52, 6346-6353.
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V. Chandrasekhar, R. K. Metre, S. Biswas, " Stabilizing the [RSn(�2-O)SnR] Motif through Intramolecular N -> Sn Coordination. Synthesis and Characterization of [(RSn)2(�2-O)(�2-O FcCOO)2)(η-FcCOO)2)]�THF and {(RSn)2(�2-O)[(t-BuO)2PO2]2Cl2}�THF �2H2O (R = 2-(Phenylazo)phenyl)", Organometallics 2013, 32, 3419-3422.
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V. Chandrasekhar, R. Suriya Narayanan"Organostannoxane-supported Pd(0) nanoparticles as an efficient catalytic system for alkyne dimerization", Ind. J. Chem. Sec. A. 2013, 52, 1066-1071.
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V. Chandrasekhar, S. Das, A. Dey, S. Hossain, F. Lloret, E. Pardo, "Synthesis, Structure, and Magnetic Properties of a Family of Heterometallic Pentanuclear [Co4Ln] (Ln = GdIII, DyIII, TbIII, and HoIII) Assemblies", Eur. J. Inorg. Chem. 2013, 4506-4514.
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V. Chandrasekhar, C. Mohapatra, R. K. Metre, "Reactions of (E)-5-(Pyridin-4-yl-methyleneamino)isophthalic Acid (LH2) with Triorganotin Oxides and Chloride. Formation of One-Dimensional- and Two-Dimensional-Coordination Polymers", Cryst. Growth Des. 2013, 13, 4607-4614.
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V. Chandrasekhar, S. Das, A. Dey, Atanu; S. Hossain, J. P. Sutter, "Tetranuclear Lanthanide(III) Complexes Containing Dimeric Subunits: Single-Molecule Magnet Behavior for the Dy4 Analogue", Inorg. Chem. 2013, 52, 11956-11965.
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V. Chandrasekhar, C. Mohapatra, "2D-Coordination Polymer Containing Interconnected 82-Membered Organotin Macrocycles", Cryst. Growth Des. 2013, 13, 4655-4658.
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V. Chandrasekhar, P. Bag, W. Kroener, K. Gieb, P. Muller, "Pentanuclear Heterometallic {Ni2Ln3}(Ln = Gd, Dy, Tb, Ho) Assemblies. Single-Molecule Magnet Behavior and Multistep Relaxation in the Dysprosium Derivative", Inorg. Chem. 2013, 52, 13078-13086.
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V. Chandrasekhar, S. Nagendran, "Heteroatomic p-Block (Main-Chain) Polymers", In �Comprehensive Inorganic Chemistry II: From Elements to Applications� Volume 1, Eds.J.Reedijk and K. Poeppelmeier. Elsevier, Oxford, U. K.
2013, 1, 823-860.
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2012
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V.Chandrasekhar, P.Singh, K. Gopal, A.Steiner, "Trapping Dimethyltin Cations by Bipyridine-N,N'-Dioxide Ligands", Zeitschrift fuer Anorganische und Allgemeine Chemie 2012, 638, 1-8.
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V. Chandrasekhar, T. Senapati, A. Dey, S. Das, M. Kalisz, R. Clerac, "Cyclo- and Carbophosphazene-Supported Ligands for the Assembly of Heterometallic (Cu2+/Ca2+, Cu2+/Dy3+, Cu2+/Tb3+) Complexes: Synthesis, Structure, and Magnetism", Inorg. Chem. 2012, 51, 2031-2038.
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V. Chandrasekhar, A. Dey, T. Senapati, S.E. Carolina, "Distorted Cubic Tetranuclear Vanadium(IV) Phosphonate Cages: Double-four-ring (D4R) Containing Transition Metal Ion Phosphonate Pages", Dalton Trans. 2012, 41, 799-803.
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V. Chandrasekhar, T. Hajra, J. K. Bera, S. M. W. Rahaman, N. Satumtira, O. Elbjeirami, M.A. Omary, "Ligand-Bridged Dinuclear Cyclometalated Ir(III) Complexes: From Metallamacrocycles to Discrete Dimers", Inorg. Chem. 2012, 51, 1319-1329.
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V. Chandrasekhar, A. Dey, S. Kundu, "Cyclophosphazene- and Cyclocarbophosphazene-Based Supported Ligands", Ind. J. Chem. Section A, 2012, 51, 118-129.
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V. Chandrasekhar, L. Nagarajan, S. Hossain, K. Gopal, S. Ghosh, S.Verma, " Multicomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages", Inorg. Chem. 2012, 51, 5605-5616
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V. Chandrasekhar, C. Mohapatra, R. J. Butcher, "Synthesis of One- and Two-Dimensional Coordination Polymers Containing Organotin Macrocycles. Reactions of (n-Bu3Sn)2O with Pyridine Dicarboxylic Acids. Structure-Directing Role of the Ancillary 4,4'-Bipyridine Ligand", Cryst. Growth Des. 2012, 12, 3285-3295
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V. Chandrasekhar, R. K. Metre, "Bismuth-Ferrocene Carboxylates: Synthesis and Structure", Dalton Trans. 2012, 41, 11684�11691
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V. Chandrasekhar, J. Goura, E. C. Sanudo, "Carboxylate-Free Manganese(II) Phosphonate Assemblies: Synthesis, Structure, and Magnetism", Inorg. Chem. 2012, 51, 8479-8487
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V. Chandrasekhar, S. Das, R. Yadav, S. Hossain, R. Parihar, G. Subramaniam, P. Sen, "Novel Chemosensor for the Visual Detection of Copper(II) in Aqueous Solution at the ppm Level", Inorg. Chem. 2012, 51, 8664-8666
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V. Chandrasekhar, B. Mahanti, P. Bandipalli, K. Bhanuprakash, "Cyclometalated Iridium(III) Complexes Containing Hydroxide/Chloride Ligands: Isolation of Heterobridged Dinuclear Iridium(III) Compounds Containing µ-OH and µ-Pyrazole Ligands", Inorg. Chem. 2012, 51, 10536-47
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2011
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V. Chandrasekhar, S. M. W. Rahaman, T. Hajra, D. Das, T. Ghatak, S. Rafiq, P. Sen, J.K. Bera, "A trinuclear Bright Red Luminophore Containing Cyclometallated Ir(III) Motifs", Chem. Commun. 2011, 47, 10836-10838.
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V. Chandrasekhar, M. D. Pandey. B. Das, B. Mahanti, K. Gopal, R. Azhakar, "Synthesis, Structure and Photo-Physical Properties of Phosphorus-Supported Fluorescent Probes", Tetrahedron 2011, 67, 6917-6926
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V. Chandrasekhar, M. D. Pandey, K. Gopal, R. Azhakar, "Assembly of a Dinuclear Silver Complex Containing an Ag2S2 Motif from a Phosphorus-Supported Trishydrazone Ligand. P=S-Ag(I) Coordination", Dalton Trans. 2011, 40, 7873-7878
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V. Chandrasekhar, M. D. Pandey, S. K. Maurya, P. Sen, D. Goswami, "Two-Photon-Absorption Technique for Selective Detection of Copper(II) Ions in Aqueous Solution Using a Dansyl-Pyrene Conjugate", J. Asian Chem. 2011, 6, 2246-2250
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V. Chandrasekhar, B. Mahanti, P. Bandipalli, K. Bhanuprakash, N. N. Nair, "Cyclometalated Ir(III) Complexes Containing N-aryl Picolinamide Ancillary Ligands", J.Organomet. Chem. 2011, 696, 2711-2719
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V. Chandrasekhar, R. S. Narayanan, " Organostannoxane-Supported Pd(0) Nanoparticles as Efficient Catalysts for Heck-Coupling Reactions", Tetrahedron Lett. 2011, 52, 3527-3531
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T. Hajra, J.K. Bera, V. Chandrasekhar, "Cyclometalated Ir(III) Complexes Containing Pyrazole/Pyrazine Carboxylate Ligands", Aust. J. Chem. 2011, 64, 561-566
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V. Chandrasekhar, M. D. Pandey, B. Das, B. Mahanti, T. Senapati, "A Phosphorus-Supported Coumarin-Containing Ligand as a Fluorescence Probe for Detection of Cu(II) and Ag(I) Ions", Ind. J. Chem. Section A 2011, 50, 453-458
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T. Hajra; J.K. Bera, V. Chandrasekhar, "Multimetallic Compounds Containing Cyclometalated Ir(III) Units: Synthesis, Structure, Electrochemistry and Photophysical Properties", Inorg. Chim. Acta 2011, 372, 53-61.
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V. Chandrasekhar, "Professor S. S. Krishnamurthy", Inorg. Chim. Acta 2011, 372, 1
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V. Chandrasekhar, T. Senapati, A. Dey, S. Hossain, "Molecular Transition-Metal Phosphonates", Dalton Trans. 2011, 40, 5394-5418
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V. Chandrasekhar, T. Senapati, A. Dey, S. Hossain, K. Gopal, "Carbophosphazene-Based Multisite Coordination Ligands: Metalation Studies on the Pyridyloxy Carbophosphazene, [NC(NMe2)]2[NP(p-OC5H4N)2]", Cryst. Growth Des. 2011, 11, 1512-1519
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V. Chandrasekhar, M. D. Pandey, "Fluorescence Sensing of Cu2+ and Hg2+ by a Dipyrene ligand Involving an Excimer-Switch off Mechanism", Tetrahedron Lett. 2011, 52, 1938-1941
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V. Chandrasekhar, V. Krishnan, R. Azhakar, T. Senapati, A. Dey, R. S. Narayanan, "Carbophosphazene-Supported Ligand Systems Containing Pyrazole/Guanidine Coordinating Groups", Inorg. Chem. 2011, 50, 2568-2579
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V. Chandrasekhar, T. Senapati, A. Dey, E. C. Sanudo, "Rational Assembly of Soluble Copper(II) Phosphonates: Synthesis, Structure and Magnetism of Molecular Tetranuclear Copper(II) Phosphonates
", Inorg. Chem. 2011, 50, 1420-1428 -
V. Chandrasekhar, P. Singh, "Reactions of in Situ Generated Hydrated Organotin Cations with Chelating O,O- or O,N-Ligands: a Possible Structure-Directing Influence of the Organic Substituent on Tin", Dalton Trans. 2011, 40, 114-123
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V. Chandrasekhar, P. Thilagar, A. Steiner, "Cryst. Growth Des., 2011, 11, 1446�1449", Cryst. Growth Des., 2011, 11, 1446�1449
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V. Chandrasekhar, R. Thirumoorthi, R. K. Metre, B. Mahanti
," Steric Control in the Reactions of 3-Pyrazolecarboxylic Acid with Diorganotin Dichlorides", J.Organomet. Chem. 2011, 696, 600-606 -
T. Hajra; J.K. Bera, V. Chandrasekhar, "Cyclometalated Ir(III) Complexes Containing Ancillary Pyrazole-Based Ligands", Ind. J. Chem. Section A 2011, 50, 1290-1297 (Special P. C. Ray issue)
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2010
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V. Chandrasekhar, A. Kumar, M. D. Pandey, "Imine-functionalized, Fluorescent Organomercury and -Tellurium Compounds", J.Organomet. Chem. 2010, 695, 74-81
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M. D. Pandey, A. K. Mishra, V. Chandrasekhar, S. Verma, "Silver-Guided Excimer Emission in an Adenine-Pyrene Conjugate: Fluorescence Lifetime and Crystal Studies", Inorg. Chem. 2010, 49, 2020-2022
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V. Chandrasekhar, R. Thirumoorthi, "Coordination Polymers Containing Ferrocene Backbone. Synthesis, Structure and Electrochemistry", Dalton Trans. 2010, 39, 2684 -2691
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V. Chandrasekhar, T. Senapati, "Trapping two different CdCl2 1D-layered Structures by a Cyclocarbophosphazene-Based Ligand", Cryst.Eng.Comm. 2010, 12, 682-684
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V. Chandrasekhar, R. Azhakar, B.M. Pandian, T. Senapati, P. Bag, M. D. Pandey, S. K. Maurya, D. Goswami, "Synthesis, Structure, and Two-Photon Absorption Studies of a Phosphorus-Based Tris Hydrazone Ligand (S)P[N(Me)N:CH-C6H3-2-OH-4-N(CH2CH3)2]3 and Its Metal Complexes", Inorg. Chem. 2010, 49, 4008-4016
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V. Chandrasekhar, P. Singh, "In Situ Generated Hydrated Diorganotin Cations as Synthons for Hydrogen-Bonded and Coordination-driven 1D-, 2D-, and 3D-Assemblies", Cryst. Growth Des. 2010, 10, 3077-3093
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V. Chandrasekhar, P. Sasikumar, T. Senapati, A. Dey, "Dinuclear Metal Phosphonates and -Phosphates", Inorg. Chim. Acta 2010, 363, 2920-2928
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V. Chandrasekhar; R. Thirumoorthi, "Synthesis and Structure of Diorganotin Dibromides, R2SnBr2 (R = 2,4,6-Trimethylphenyl or 2,4,6-Trimethylbenzyl): Hydrolysis of (2,4,6-Me3C6H2CH2)2SnBr2", J. Chem. Sci. 2010, 122, 687-695
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2009
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V. Chandrasekhar, P. Singh, "First Example of a Hydrated Monoorganotin Cation: Synthesis and Structure of [{PhSn(H2O)3(m -OH)}2][{1,5-C10H6-(SO3)2}2]", Organometallics 2009, 28, 42-44
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V. Chandrasekhar, B.M. Pandian, J.J. Vittal, R. Clérac, "Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L2Co2Ln][X]} [Ln = Eu, X = Cl; Ln = Tb, Dy, Ho, X = NO3; LH3 = (S)P[N(Me)N=CH-C6H3-2-OH-3-OMe]3]: A 3d-4f Family of Single-Molecule Magnets", Inorg. Chem. 2009, 48, 1148-1157
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V. Chandrasekhar, R. Thirumoorthi, "Reactions of 3,5-Pyrazoledicarboxylic Acid with Organotin Chlorides and Oxides. Coordination Polymers Containing Organotin Macrocycles", Organometallics 2009, 28, 2096-2106
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V. Chandrasekhar, R. Thirumoorthi, "A Nonanuclear Organostiboxane Cage", Organometallics 2009, 28, 2637-2639
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V. Chandrasekhar, T. Senapati, R. Clerac,"Dinuclear Copper(II) Phosphonates Containing Chelating Nitrogen Ligands: Synthesis, Structure, Magnetism and Nuclease Activity", Eur. J. Inorg. Chem. 2009, 12, 1640-1646
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V. Chandrasekhar, M. D. Pandey, P. Bag, S. Pandey, "A modular Ligand Design for Cation Sensors: Phosphorus-Supported Pyrene-Containing Ligands as Efficient Cu(II) and Mg(II) Sensors", Tetrahedron 2009, 65, 4540-4546
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V.Chandrasekhar, T. Senapati, E. C. Sanudo, R. Clerac, "Tri-, Tetra-, and Hexanuclear Copper(II) Phosphonates Containing N-Donor Chelating Ligands:Synthesis, Structure, Magnetic Properties, and Nuclease Activity", Inorg. Chem. 2009, 48, 6192-6204
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V. Chandrasekhar, R. Thirumoorthi, "Tellurasiloxane Cages Containing Te6Si4O12 and Te6Si6O15 Frameworks", Inorg. Chem. 2009, 48, 6236-6241
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V. Chandrasekhar, A. Kumar, "Assembly of Diverse Structural Types of Organotellurium Compounds in the Reactions of (4-MeO-C6H4)2TeO with pyridine carboxylic acids", J.Organomet. Chem. 2009, 694, 2628-2635
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V. Chandrasekhar, B. M. Pandian, "Phosphorus-Supported Ligands for the Assembly of Multimetal Architectures.", Acc. Chem. Res. 2009, 42, 1047-1062
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V. Chandrasekhar, K. Gopal, P. Singh, R. S. Narayanan, A. Duthie, "Self-Assembly of Organostannoxanes: Formation of Gels in Aromatic Solvents", Organometallics 2009, 28, 4593-4601
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V. Chandrasekhar, P. Singh, "A Pentahydrated Diorganotin Cation. Cocrystallization of [{n-Bu2Sn(H2O)5}][CF3SO3]2 and [{n-Bu2Sn(BPDO-II)2(H2O)2}][CF3SO3]2", Organometallics 2009, 28, 4974-4978
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V. Chandrasekhar, L. Nagarajan, "A hexadecameric Copper(II) Phosphonate", Dalton Trans. 2009, 34, 6712 -6714
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V. Chandrasekhar, R. S. Narayanan, P. Thilagar, "Organostannoxane-Supported Palladium Nanoparticles. Highly Efficient Catalysts for Suzuki-Coupling Reactions", Organometallics 2009, 28, 5883-5888
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V. Chandrasekhar, R. Thirumoorthi, "Halide-Capped Tellurium-Containing Macrocycles", Inorg. Chem. 2009, 48, 10330-10337
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V. Chandrasekhar, P. Bag, M. D. Pandey, "Phosphorus-Supported Multidentate Coumarin-Containing Fluorescence Sensors for Cu2+", Tetrahedron 2009, 65, 9876-9883
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2008
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V. Chandrasekhar, B. M. Pandian, R. Azhakar, "Synthesis, Structure and Metallation of Spiro-N3P3(O2C12H8)(OC5H4N-2)4:A Heptacoordinate Co(II) in the Molecular Structure of N3P3(O2C12H8)(OC5H4N-2)4 �Co(NO3)2", Polyhedron 2008, 27, 255-262
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V. Chandrasekhar, L. Nagarajan, R. Clerac, S. Ghosh, S. Verma, "Synthesis, Structure, Magnetism and Nuclease Activity of Tetranuclear Copper(II) Phosphonates Containing Ancillary 2,2′-Bipyridine or 1,10-Phenanthroline Ligands", Inorg. Chem. 2008, 47, 1067-1073
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V. Chandrasekhar, G. T. S. Andavan, R. Azhakar, B. M. Pandian, "Cyclophosphazene-Supported Tetranuclear Copper Assembly Containing 15 Contiguous Inorganic Rings", Inorg. Chem. 2008, 47, 1922-1924
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V. Chandrasekhar, R. Azhakar, T. Senapati, P. Thilagar, S. Ghosh, S. Verma, R. Boomishankar, A. Steiner, P. K�gerler, "A Distorted Cubic Tetranuclear Copper(II) Phosphonate Cage with a Double-Four-Ring-Type Core", Dalton Trans. 2008, 9, 1150-1160
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V. Chandrasekhar, P. Sasikumar, P. Singh, R. Thirumoorthi, T. Senapati, "Multi-Functional Architectures Supported on Organostannoxane Scaffolds", J. Chem. Sci. 2008, 120, 105-113
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V. Chandrasekhar, R. Azhakar, B.M.Pandian, J.F.Bickley, A. Steiner, "A tunable Coordination Response of the Phosphorus-Based Hexadentate Ligand (S)P[N(Me)N=CHC6H4-o-OH]3 (LH3): Synthesis and Structure of LM (M = Sc, Cr, Mn, Fe, Co, Ga)", Eur. J. Inorg. Chem. 2008, 7, 1116-1124
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V. Chandrasekhar, B.M. Pandian, R. Azhakar, R. Boomishankar, A. Steiner , J.J. Vittal, A. Houri, R. Clérac, "Trinuclear Heterobimetallic Ni2Ln complexes [L2Ni2Ln][ClO4] (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er; LH3 = (S)P[N(Me)NCH-C6H3-2-OH-3-OMe]3): From Simple Paramagnetic Complexes to Single-Molecule Magnet Behavior", Inorg. Chem. 2008, 47, 4918-4929
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V. Chandrasekhar, L. Nagarajan, R. Clerac, S. Ghosh, T. Senapati, S. Verma, "Barrel- and Crown-Shaped Dodecanuclear Copper(II) Cages Built from Phosphonate, Pyrazole, and Hydroxide Ligands", Inorg. Chem. 2008, 47, 5347-5354
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V. Chandrasekhar, P. Singh, "Trapping a Discrete [R2Sn(m-OH)SnR2] Motif. Synthesis and Structural Characterization of [{(Phen)(NO3)Me2Sn(m-OH)SnMe2(NO3)(Phen)}{NO3}] (Phen = 1,10-Phenanthroline)", Organometallics 2008, 27, 4083-4087
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V. Chandrasekhar, T. Senapati, E. C. Sanudo, "Synthesis, Structure, and Magnetism of Hexanuclear Copper(II) Phosphonates", Inorg. Chem. 2008, 47, 9553-9560
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V. Chandrasekhar, P. Sasikumar, R. Boomishankar, "Assembly of tetra, di and mononuclear molecular cadmium phosphonates using 2,4,6-triisopropylphenylphosponic acid and ancillary ligands", Dalton Trans. 2008, 38, 5189 - 5196
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V. Chandrasekhar, B.M. Pandian, R. Boomishankar, A. Steiner, R. Clérac, "Synthesis, structure and magnetic properties of linear heterobimetallic trinuclear Mn2Ln (Ln = Eu, Gd, Dy) complexes", Dalton Trans. 2008, 38, 5143 - 5145
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V. Chandrasekhar, R. Thirumoorthi, "Facile, Ambient Temperature, Double Sn-C Bond Cleavage: Synthesis, Structure, and Electrochemistry of Organotin and Organo�tellurium Ferrocenecarboxylates ", Eur. J. Inorg. Chem. 2008, 29, 4578-4585
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2007
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V. Chandrasekhar, R. Thirumoorthi, R. Azhakar, " New Structural Forms of Organostannoxane Macrocycle Networks", Organometallics 2007, 26, 26-29
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V. Chandrasekhar, P. Thilagar, V. Krishnan, J. F. Bickley, A. Steiner, "Click Synthesis of Fluorine-Rich Cyclotriphosphazene Hydrazones. Synthesis and Supramolecular Structures of N3P3(N(Me)N=CHC6F5)6, spiro-N3P3(C12H8O2)(N(Me)N=CHC6F5)4, and Dispiro-N3P3(C12H8O2)", Cryst. Growth Des. 2007, 7, 668-675
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V. Chandrasekhar, P. Thilagar, B. M. Pandian, "Cyclophosphazene-Based Multi-site Coordination Ligands", Coord. Chem. Rev. 2007, 251, 1045-1074
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V. Chandrasekhar, P. Thilagar, T. Senapati, "Transition Metal-assisted Hydrolysis of Pyrazole-appended Organooxotin Carboxylates Accompanied by Ligand Transfer", Eur. J. Inorg. Chem. 2007, 7, 1004-1009
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V. Chandrasekhar, P. Singh, K. Gopal, "Direct hydrolysis of hydrated organotin cations: Synthesis and structural characterization of {[n-Bu2Sn(OH2)(Phen)(O3SC6H3-2,5-Me2)]+[2,5- Me2C6H3SO3]-...", Organometallics 2007, 26, 2833-2839
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V. Chandrasekhar, K. Gopal, P. Thilagar, "Nanodimensional organostannoxane molecular assemblies", Acc. Chem. Res. 2007, 40, 420-434
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V.Chandrasekhar, V. Krishnan, P. Sasikumar, V. S. R. Murthy, " Chemically cross-linked polysilanes as stable polymer precursors for conversion to silicon carbide", J. Inorg. Organomet. Polym. Mater. 2007, 17, 439-446
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V. Chandrasekhar, B. M. Pandian, R. Azhakar, J. J. Vittal, R. Clérac, " Linear trinuclear mixed-metal CoII-GdIII-Co II single-molecule magnet: [L2Co2Gd][NO3]�2CHCl3 (LH3 = (S)P[N(Me)N=CH-C6H3-2-OH-3-OMe]3)", Inorg. Chem. 2007, 46, 5140-5142
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V.Chandrasekhar, P. Singh, K. Gopal, "Organotin compounds containing four-membered distannoxane [Sn(µ-OH)]2 units", Appl. Organomet. Chem. 2007, 21, 483-503
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V. Chandrasekhar, P. Sasikumar, P. Thilagar, "Formation of a double-bicapped hexatin phosphate cage by a de-arylation reaction. Synthesis and structure of [(PhSn)6(-OH)2(µ-OEt)4{(ArO)PO3}4] (Ar = 2,6-i-Pr2C6H3)", Organometallics 2007, 26, 4386-4388
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V. Chandrasekhar, R.Thirumoorthi, "1,1′-Ferrocenedicarboxylate-Bridged Redox-Active Oorganotin and -Tellurium-Containing 16-Membered Macrocycles: Synthesis, Structure, and Electrochemistry", Organometallics 2007, 26, 5415-5422
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V. Chandrasekhar, G. T. S. Andavan, R. Azhakar, B. M. Pandian, "42- and 46-Membered Phosphorus-Based Macrocycles", Synth. React. Inorg. Met-Org. Nano-Met. Chem. 2007, 37, 725-728
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V. Chandrasekhar, "Molecule Matters: High oxidation State: FeVI in an Octahedral Coordination Complex", Resonance 2007, 12, 64-73.
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2006
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V. Chandrasekhar, K. Gopal, S. Nagendran, A. Steiner, S. Zacchini, "Influence of Aromatic Substituents on the Supramolecular Architectures of Monoorganooxotin Drums", Cryst. Growth Des. 2006, 6, 267-273
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V. Chandrasekhar, P. Thilagar, P. Sasikumar, "A Multi-Site Coordination Ligands Assembled on Organostannoxane Supports", J. Organomet. Chem. 2006, 691, 1681-1692
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V. Chandrasekhar, R. Azhakar, J. F. Bickley, A. Steiner, "Influence of O-H---O=P Hydrogen-bonding on the Supramolecular Architectures of Phosphorus based Hydrazones: Alternate Right- and Left-handed Helical Chains in the Crystal Structure of C6H5P(O)[N(CH3)N=CHC6H4-p-OH]2", Cryst. Growth Des. 2006, 6, 910-914
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V. Chandrasekhar, P. Sasikumar, R. Boomishankar, G. Anantharaman, "Assembly of Lipophilic Tetranuclear (Cu4 and Zn4) Molecular Metallophosphonates from 2,4,6-Triisopropylphenylphosponic acid and Pyrazole Ligands", Inorg. Chem. 2006, 45, 3344-3351
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V. Chandrasekhar, B.M. Pandian, R. Azhakar, "Di- and Trinuclear Complexes Derived from Hexakis(2-pyridyloxy)cyclotriphosphazene. Unusual P-O Bond Cleavage in the Formation of [{(L�CuCl)2(Co(NO3)}Cl] (L� = N3P3(OC5H4N)5(O))", Inorg. Chem. 2006, 45, 3510-3518
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V. Chandrasekhar, R. Azhakar, V. Krishnan, A. Athimoolam, B.M. Pandian, "Cyclocarbophosphazene Containing Tetrameric Assemblies Formed by the Mediation of P-O-P and P-O-Cu linkages", J. Am. Chem. Soc. 2006, 128, 6802-6803
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V. Chandrasekhar, P. Thilagar, J. F. Bickley, A. Steiner, "Inorganic-Cored Photoactive Assemblies: Synthesis, Structure, and Photochemical Investigations on Stannoxane-Supported Multifluorene Compounds", Chem. Eur. J. 2006, 12, 8847-8861
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V. Chandrasekhar, R. Boomishankar, K. Gopal, P. Sasikumar, P. Singh, A. Steiner, S. Zacchini, "Synthesis, Structure and Reactivity of Hydrated and Dehydrated Organotin Cations", Eur. J. Inorg. Chem. 2006, 20, 4129-4136
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V. Chandrasekhar, K. Gopal, L. Nagarajan, P. Sasikumar, P. Thilagar, "Stannoxanes and phosphonates: New approaches in organometallic and transition metal assemblies", J. Chem. Sci. 2006, 118, 455-462
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V.Chandrasekhar, G. T. S. Andavan, R. Azhakar, B. M. Pandian, "36- and 42-Membered cyclophosphazene-containing macrocycles", Tetrahedron Lett. 2006, 47, 8365-8368
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2005
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U. N. Nehete, V. Chandrasekhar, H. W. Roesky, J. Magull“The Formal Conversion of SiOH Protons into Hydrides by Germanium(II) Species Leads to the Formation of the Germanium(IV) Hydride Cluster [(RSiO3GeH)4]”Angew. Chem. Int. Ed. 2005, 44, 281 – 284
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V. Chandrasekhar, R. Azhakar, J. F. Bickley, A. Steiner“A luminescent linear trinuclear magnesium complex assembled from a phosphorus-based tris-hydrazone ligand”Chem. Commun. 2005, 459-461
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V. Chandrasekhar, K. Gopal“Monoorganotin(IV) phosphonates”Appl. Organometal. Chem. 2005, 19, 429-436
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V. Chandrasekhar, S. Nagendran, R. Azhakar, M. Ravi Kumar, A. Srinivasan, K. Ray, T. K. Chandrashekar, C. Madhavaiah, S. Verma, U. Deva Priyakumar, G. N. Sastry“ A Lipophilic Hexaporphyrin Assembly Supported on a Stannoxane Core”J. Am. Chem. Soc. 2005,127, 2410-2411
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V. Chandrasekhar, V. Krishnan, R. Azhakar, C. Madhavaiah, S. Verma“Biocatalysis by metallated cyclotriphosphazenes: L2Zn(NO3)2 {L = spiro-N3P3[O2C12H8][N(CH3)NH2]} as a synthetic phosphoesterase and nuclease”J. Chem. Sci. 2005, 43, 175-178
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V. Chandrasekhar, A. Athimoolam, V. Krishnan, R. Azhakar, C. Madhavaiah, S. Verma“A Copper-Metalated, Hybrid Inorganic-Organic Polymer as an Oxidative Nuclease ”Eur. J. Inorg. Chem. 2005, 1482 – 1486
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V. Chandrasekhar, R. Boomishankar, R. Azhakar, K. Gopal, A. Steiner, S. Zacchini“N-Bonded Monosilanols: Synthesis and Characterization of ArN(SiMe3)SiMe2Cl and ArN(SiMe3)SiMe2OH (Ar = C6H5; 2,6-Me2C6H3; 2,6-iPr2C6H3) ”Eur. J. Inorg. Chem. 2005, 1880 - 18856
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V. Chandrasekhar, R. Azhakar“A tubular architecture in a phosphorus based trihydrazide, {P(S)[N(CH3)NH2]3} ”CrystEngComm. 2005, 7, 346-349
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V. Chandrasekhar, R. Azhakar, S. Zacchini, J. F. Bickley, A. Steiner“Synthesis, Structure, and Stereochemistry of Trinuclear Metal Complexes Formed from the Phosphorus-Based Achiral Tripodal Ligand {P(S)[N(Me)N=CHC6H4o-OH]3} (LH3): Luminescent Properties of L2Cd3.2H2O ”Inorg. Chem. 2005, 44, 4608-4615
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V. Chandrasekhar, K. Gopal, S. Nagendran, P. Singh, A. Steiner, S. Zacchini, J. F. Bickley“Organostannoxane Supported Multi-Ferrocenyl Assemblies: Synthesis, Novel Supramolecular Structures and Electrochemistry ”Chem. Eur. J. 2005, 11, 5437-5448
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V. Chandrasekhar, L. Nagarajan, K. Gopal, V. Baskar, P. Koegerler“A new structural form for a decanuclear copper(II) assembly ”Dalton. Trans (Commun). 2005, 3143-3145
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V. Chandrasekhar, V. Baskar, K. Gopal, J. J. Vittal“Organooxotincages, {[(n-BuSn)3(μ3-O)(OC6H4-4-X)3]2[HPO3]4}, X = H, Cl, Br and I in Double O-Capped Strcutures: Halogen-Bonding-Mediated Supramolecular Formation ”Organometallics 2005, 24, 4926-4932
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V. Chandrasekhar, K. Gopal, P. Sasikumar, R. Thirumoorthi“Organooxotin assemblies from Sn-C bond cleavage reactions ”Coord. Chem. Rev. 2005, 249, 1745-1765
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V. Chandrasekhar, P. Thilagar, J. F. Bickley, A. Steiner“Alternating Hydrophilic and Hydrophobic pockets in the Channel Structures of Organostannoxane Prismanes: Preferential confinement of Guest Molecules”J. Am. Chem. Soc. 2005, 127, 11556-11557
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V. Chandrasekhar, R. Boomishankar, P. Sasikumar, L. Nagarajan, A. W. Cordes“Mononuclear metal phosphinates with ancillary pyrazole ligands. Synthesis and X-ray crystal structures of [M(Ph2PO2)2(3,5-DMPZ)2] [M=Co,Zn]”Z. Anorg. Allg. Chem. 2005, 631, 2727-2732 (Special Issue in honor of Prof. H. W. Roesky)
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V. Chandrasekhar“Inorganic and Organometallic Polymers”Springer-Verlag, Heidelberg, Germany, 2005
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2004
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V. Chandrasekhar, V. Krishnan“Coordination chemistry of cyclophosphazenes”Phosphazenes. Eds. M. Gleria, R. Jaeger 2004, 827-852, Nova Publishers, Hauppauge, NY.
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V. Chandrasekhar, V. Krishnan, A. Steiner, J. F. Bickley“Cyclophosphazene hydrazides as efficient multisite coordination ligands. η3-fac-non-geminal-N3 coordination of spiro-N3P3[O2C12H8][N(Me)NH2]4 (L) in L2CoCl3 and L2M(NO3)2 (M = Ni, Zn, Cd)”Inorg. Chem. 2004, 43, 166-172
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V. Chandrasekhar, P. Deria, V. Krishnan, A. Athimoolam, S. Singh, C. Madhavaiah, S.G. Srivatsan, S. Verma“Metalated hybrid polymers as catalytic reagents for phosphate ester hydrolysis and plasmid modification ”Bioorg. Med. Chem. Lett. 2004, 14, 1559-1562
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V. Chandrasekhar, V. Basker, A. Steiner, S, Zacchini “Reactions of n-Bu2SnO and (n-Bu3Sn)2O with 1,1,2,3,3-pentamethyltrimethylene phosphinic acid: Synthesis and X-ray crystal structures of a novel spirocyclic coordination polymer and a 16-membered inorganic macrocycle ” Organometallics 2004, 23, 1390-1395
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G. Anantharaman, V. Chandrasekhar, M. G. Walawalkar, H. W. Roesky, D. Viidovic, J. Magull M. Noltemeyer “Molecular zinc phosphonates: synthesis and X-ray crystal structures of [{(ZnMe)4(THF)2}{tBuPO3}2] and [{(ZnEt)3(Zn(THF))3}{tBuPO3}4{µ3-OEt}] ” Dalton Transactions 2004, 1271-1275
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G. Anantharaman, V. Chandrasekhar, U. N. Nehete, H. W. Roesky, D. Vidovic, and J. Magull“New Polyhedral Zinc Siloxanes: Synthesis and X-ray Crystal Structures of Zn8Me7(dioxane)2(O3SiR)3 and [Zn7Me2(THF)5(O3SiR)4] [R = (2,6-i-Pr2C6H3)N(SiMe3)] ” Organometallics, 2004, 23, 2251-2256
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V. Chandrasekhar, V. Basker, R. Boomishankar, S. Nagendran “Organostannoxane Motifs in Cages and Supramolecular Architectures. ” Phosphorus, Sulfur, Silicon and the Related Elements, 2004, 179, 699-701
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S. Shravan Kumar, J. Rong, ; S. Singh, ; H. W. Roesky, D. Vidovic, J. Magull, D. Neculai, V. Chandrasekhar, M. Baldus“Synthesis and Reactivity of the Carbaalanes (AlH)6(AlNMe3)2(CCH2C5H4FeC5H5)6 and (AlH)6(AlNMe3)2(CCH2Ph)6: X-ray Crystal Structure of (AlH)6(AlNMe3)2-(CCH2C5H4FeC5H5)6 ”Organometallics, 2004, 23, 3496-3500
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U. N. Nehete, G. Anantharaman, V. Chandrasekhar, R. Murugavel, M. G. Walawalkar, H. W. Roesky, D. Vidovic, J. Magull, K. Samwer, B. Sass “Polyhedral Ferrous and Ferric Siloxanes ”Angew. Chem. Int. Ed., 2004, 43, 3832 - 3835
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U. N. Nehete, V. Chandrasekhar, G. Anantharaman, H. W. Roesky, D. Vidovic, J. Magull “Molecular {(SnO)6} Trapped by Two {R2Si2O3} Fragments: X-Ray Single-Crystal Structure of [(SnO)6(R2Si2O3)2 Synthesis and X-ray Structure of a Novel Organosoluble Zirconium Phosphonate”Inorg. Chem. 2000, 39, 23-36
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V. Chandrasekhar, S. Nagendran, S. Bansal, D. R. Powell“An Iron Wheel on a Tin Drum: A Novel Assembly of a Hexa Ferrocene Unit on a Tin-oxygen Cluster”Angew. Chem. Int. Edn. Engl. 2000, 39, 1833
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V. Chandrasekhar, S. Nagendran, S. Kingsley, V. Krishnan, R. Boomishankar.“Si-O and P-O Motifs in Inorganic Rings and Clusters.”Proc. Ind. Acad. Sci. 2000, 112, 171-178
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V. Chandrasekhar, S. Kingsley“A Dodecanuclear Copper(II) Cage Containing Phosphonate Ligands”Angew. Chem. Int. Edn. Engl. 2000, 39, 2320
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V. Chandrasekhar, S. Kingsley, A. Vij, K. C. Lam, A. L. Rheingold“Formation of a Tetranuclear Copper(II) Cluster Assembled by a Metal Assisted Hydrolysis and Desulfurization of Bis(3,5-dimethyl pyrazolyl)methyl phosphine sulfide, MeP(S)(3,5-Me2Pz)2”Inorg. Chem. 2000, 39, 3238-3242
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1999
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K. R. Justin Thomas, V. Chandrasekhar, K. Vivekanandan, G. T. Senthil Andavan, S. Nagendran, S. Kingsley, E. R. T. Tiekink “Tridentate N3 Capping Coordination Behavior of Potentially Multi-site Coordinating Cyclophosphazenes: Synthesis and Spectroscopic Studies of 2,2-spiro(1,3-propanediamino)-4,4,6,6-tetrakis(3,5-dimethylpyrazolyl)-cyclotriphosphazene and their Mononuclear complexes; X-ray Structure of ATPCTP.CoCl2”Inorg. Chim. Acta. 1999, 286, 127-133
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V. Chandrasekhar, A. P. Athimoolam, K. Vivekanandan, S. Nagendran“New Approach for the Assembly of a Multi-site Coordinating Polymeric Ligand: Synthesis of a Pendant Pyrazolyl Cyclotriphosphazene Containing Polymer”Tetrahedron Letters 1999, 40, 1185-1186
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R. Murugavel, V. Chandrasekhar“Monovalent Group 13 Organometallic Compounds: Weakly Associated to Mmonomeric and also Versatile 2e donors”Angew. Chem. Int. Ed. Engl. 1999, 38, 1211-1215
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V. Chandrasekhar, S. Nagendran, A. Athimoolam.“Polymer Electrolyes based on Oligoetheroxy Side Chain Containing Polymers”Main Group Chemistry News 1999, 7, 4-13
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V. Chandrasekhar, S. Nagendran, R. J. Butcher“Synthesis and Characterization of New Organosilanediols with Si-N Bonds.”Organometallics 1999, 18, 4488-4492
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V. Chandrasekhar“Molecule of the month: A Stable Dibismuthene- A compound with a Bi-Bi double bond”Resonance 1999, 4, 70-74
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1998
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I. Immanuel Selvaraj, S. Chaklanobis, V. Chandrasekhar “New Lipophilic Cyclo- and Polyphosphazenes Containing Surfactant Substituents”Polymer Internationa. 1998, 46, 111-116
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V. Chandrasekhar “Polymer Solid Electrolytes: Synthesis and Structure”Advances in Polymer Science 1998, 135,139-206
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V. Chandrasekhar, K. Vivekanandan, S. Nagendran, G. T. S. Andavan, N. R. Weathers, J. C. Yarbrough, A. W. Cordes “Cycloalkylaminocyclo- and Polyphosphazenes: X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino) Dichlorocyclotriphosphazene and Octakis(cyclopropylamino) cyclotetraphosphazene”Inorg. Chem. 1998, 37, 6192-6198
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V. Chandrasekhar, S. Nagendran, Samiksha , G. T. S. Andavan “Hypervalent Tris(catecholato)silicate derived from Rice Husk Ash”Tetrahedron Letters 1998, 39, 8505-8508
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1994-97
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K. Vivekanandan, V. Chandrasekhar“Polymeric Ligands Based on Pyrazolyl Cyclophosphazene Structural Motifs”Polym. Sci. Ed. I. S. Bharadwaj. 1994,1,473-6
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E. Sampath Kumar, I. I. Selvaraj, V. Chandrasekhar“New Hybrid Organic-inorganic Polymers Containing Cyclophosphazene Pendant Groups.”Polym. Sci. Ed. I. S. Bharadwaj. 1994, 1, 470-2
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I. I. Selvaraj, S. Chaklanobis, V. Chandrasekhar“Oligoetheroxy Side-chain Containing Polyphosphazenes: Materials for Ion Transport.”Polym. Sci. Ed. I. S. Bharadwaj. 1994, 1, 403-6
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K. R. Justin Thomas, P. Tharmaraj, V. Chandrasekhar, E. R. T. Tiekink“Synthesis and Characterization of Mononuclear Ni(II) and Co(II) Complexes of 2,2-Diphenyl,4,4,6,6-tetrakis(3,5-dimethyl pyrazolyl)cyclotriphosphazene: X-ray Structure of [Ni(TPCTP)Cl2”J. Chem. Soc. Dalton Trans. 1994, 1301-1304
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K. R. Justin Thomas, P. Tharmaraj, V. Chandrasekhar, C. D. Bryan, A. W. Cordes.“Synthesis, Spectroscopy and Electrochemistry of Ternary Copper(II) Complexes with 2,2-Diphenyl,4,4,6,6-tetrakis(3,5-dimethyl pyrazolyl) Cyclotriphosphazene and Nitrogenous bases.X-ray Structures of N3P3Ph2(3,5-Me2Pz)4.Cu(ClO4)2.2H2O and N3P3Ph2(3,5-Me2Pz)4.Cu(ClO4)2.ImH”Inorg. Chem. 1994, 33, 5382-5390
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V. Chandrasekhar, K. R. J. Thomas, A. W. Cordes, S. Folkert, C. D.Bryan“2,2,4,4-Tetrakis(3,5-dimethyl pyrazol-1-y)-2 λ5, 4 λ5, 6 λ5- cyclotriphosphaza-1,3,5-triene-6-spiro-2',1',3'-diaza-2'-phosphacyclohexane, C23H36N13P3 ”Acta.Cryst. 1994, 150C, 1976-1978.
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V. Chandrasekhar, I. V. Baca, T. Chivers, T. Ziegler“Experimental and theoretical investigations of 1,4,5,7-dithiadiazepines ”Phosphorus, Sulfur, Silicon and Related Elements. 1994, 93-94, 447-448
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R. R. Holmes, J. M. Holmes, R.O. Day, K. C. Kumara Swamy, V. Chandrasekhar“Synthesis and Molecular Structures of Fluorophosphoranes, R3PF2, Isoelectronic with Anionic Fluorosilicates ”Phosphorus, Sulfur, Silicon and Related Elements. 1995, 103, 153
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I. I. Selvaraj, S. Chaklanobis, V. Chandrasekhar“Conductivity Studies on Poly(methoxy ethoxy ethoxy ethyl)methacrylate-lithium salt Complexes ”J. Electrochem.Soc. 1995, 142, 366-370
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S. Folkert, C. D. Bryan, A. W. Cordes, P. Tharmaraj,V. Chandrasekhar“Bis(bis(3,5-dimethyl-1-pyrazolyl)phosphinato)copper(II) [Cu{O2P(N2C3HMe2)2}2] ”Acta.Cryst. 1995, C51, 863-865
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E. Sampath Kumar, M. G. Muralidhara , V. Chandrasekhar“Reactions of N-methyl 1-3-diaminopropane with N3P3Cl6 and gem-N3P3Cl4Ph2 leading to Spirocyclic Products”Polyhedron 1995, 14, 1571
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K. R. Justin Thomas, P. Tharmaraj, V. Chandrasekhar, S. R. Scott, A. W. Cordes“Five Coordinate Copper(II) Complexes of gem- N3P3Ph2(dmpz)4”Polyhedron 1995, 14, 977-982
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K. R. Justin Thomas, V. Chandrasekhar, S. R. Scott, A. W. Cordes“Copper(II) and Cobalt(II) Complexes of 2,2-Diphenyl-4,4,6,6-tetrakis(1-pyrazolyl)-cyclotriphosphazene,N3P3Ph2Pz4. X-ray Crystal Structure of N3P3Ph2Pz4.CoCl2. 0.5CH2Cl2”Polyhedron 1995, 14, 1607–1613
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I.I.Selvaraj, S.Chaklanobis, P.Manoravi, V. Chandrasekhar“Conductivity studies on poly(MEEMA)-LiCF3SO3 polymer electrolyte systems”Polymer. 1995, 26, 2603-2606
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K. R. Justin Thomas, V. Chandrasekhar, C. D. Bryan, A. W. Cordes“Heterobimetallic (Pd, Pt, Cu) Complexes of Hexapyrazolyl Cyclotriphosphazene via Simultaneous geminal (N2) and nongeminal (N3) Coordination modes”J. Coord. Chem. 1995, 35, 337-348
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I.I.Selvaraj, S.Chaklanobis, V.Chandrasekhar“Synthesis and ionic conductivity studies of new water insoluble polyphosphazene polymer electrolytes”J.Electrochem.Soc. 1995, 142, 3434-3437
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R. Murugavel, V. Chandrasekhar, A. Voigt, H. W. Roesky, H. G. Schmidt, M. Noltemeyer“New Lipophilic Air-stable Silanetriols: First Example of an X-ray Crystal Structure of a Silanetriol with Si-N Bonds”Organometallics 1995, 14, 5298-5301
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R.Murugavel, V.Chandrasekhar, H.W.Roesky“Discrete silanetriols: Building blocks for three-dimensional metallasiloxanes”Acc.Chem.Res. 1996, 29, 183-189
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R. Murugavel, A. Voigt, V. Chandrasekhar, H. W. Roesky, H. G. Schmidt, M. Noltemeyer“Silanediols Derived from Silanetriols: X-ray Crystal Structures of (2,3,6,-Me3C6H2)N(SiMe3)Si(OSiMe)3(OH)2 and (2,4,6,-Me3C6H2)N(SiMe3)Si(OSiMe2R)(OH)2 [R=CH2(2-NH2-3,5-Me2C6H2)]”Chem. Ber. 1996, 129, 391-395
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V. Chandrasekhar, R. Murugavel, A. Voigt, H. W. Roesky, H. G. Schmidt, M. Noltemeyer“Cyclic and Polyhedral Aluminosiloxanes with Al2Si2O4, Al4Si2O6 and Al4Si4O12 Frameworks: X-ray Crystal Structures of [ (2,4,6,-Me3C6H2)N(SiMe3)Si(OAlBu-i)2 (OAl(Bu-i)2O]2 and [(2,6-Me2C6H3)N(SiMe3)SiO3Al.C4H8O2]4”Organometallics 1996, 15, 918-922
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A. Voigt, R. Murugavel, V. Chandrasekhar, N. Winkhofer, H. W. Roesky, H. G. Schmidt, I. Uson“Facile and Rational Route for High-yield Synthesis of Titanosiloxanes from Aminosilanetriols”Organometallics 1996, 15, 1610-1613
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V. Chandrasekhar, A. Chandrasekharan, R. O. Day, J. M. Holmes, R. R. Holmes“Novel Cyclic Pentacoordinate and Pseudopentacoordinate Lead Compounds”Phosphorus Sulfur Silicon and Related Elements 1996, 115, 125-139
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V. Chandrasekhar, T. Chivers, L. Ellis, I. Krouse, M. Parvez, I. Vargas Baca“Intramolecular Redox Cyclization upon Oxidation of a Sulfur(II) Containing Diazene: X-ray Structures of PhS(O)NC(AR)NNC(Ar)=NSO2Ph (Ar = 4-CH3C6H4) and MeSO2N(4-CH3C6H4)CN=N(C6H4 CH3-4) NSO2Me”Can. J. Chem, 1997, 75, 1188-1194
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V. Chandrasekhar, T. Chivers, M. Parvez, I. Vargas Baca, T. Ziegler“Experimental and Theoretical Studies on 1,4,5,7-Dithiadiazapinyl Radicals: Preparation and X-ray Structure of (5-(trimethylsilyl)tetrachlorobenenzo-1,4,5,7-dithiadiazepine”Inorg. Chem. 1997, 36, 4772-4777
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K.R.Justin Thomas, V.Chandrasekhar, P.Zanello, F.Laschi“Platinum(II) and palladium(II) complexes of tetrakis(pyrazolyl) cyclotri phosphazenes”Polyhedron. 1997, 16, 1003-1011
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I. Immanuel Selvaraj, V. Chandrasekhar“Copolymerization of 2-(4'-vinyl-biphenylyloxy) Pentachlorocyclotriphosphazene with Acrylate and Methacrylate monomers”Polymer 1997, 38, 3617-3623
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1988-93
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R. R. Holmes, S. Shafiezad, V. Chandrasekhar, A. C. Sau, J. M. Holmes, R. O. Day“New Five and Six Coordinated Anionic Tin(IV) complexes. Molecular Structures of Spirocyclic Stannates with Mixed Ligands”J. Am. Chem. Soc. 1988, 110, 1168-1174
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R. R. Holmes, S. Shafiezad, V. Chandrasekhar, J. M. Holmes, R. O. Day“Hydrolysis Reactions Leading to Ring Containing Hexa Coordinated Distannoxanes. Tin-Sulphur vs Tin-Oxygen Bonding”J. Am. Chem. Soc. 1988, 110, 1174-1180
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V. Chandrasekhar, P. R. Srinivasan, S. Sivaram“Recent Developments in Ziegler-Natta Catalysts for Olefin Polymerization and their Processes”Ind. J. Tech. 1988, 26, 53-82
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V. Chandrasekhar, R. O. Day, J. M. Holmes, R. R. Holmes“Mononuclear and Tetranuclear Diorganotin(IV) Carboxylates from the Reaction of Dimethyltin Oxide with Anthranilic Acid and its p-Amino Isomer”Inorg. Chem. 1988, 27, 958-964
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R. R. Holmes, R. O. Day, V. Chandrasekhar, C. G. Schmid, K. C. Kumaraswamy, J. M. Holmes“A New Class of Oligomeric Organotin Compounds”A. C. S.Symposium Series. 1988, 360, 469-482
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R. O. Day, V. Chandrasehkar, K. C. Kumaraswamy, J. M. Holmes, S. D. Burton, R. . Holmes“Novel Drums and Mixed Drum Organotin Clusters from Carboxylic, Phosphinic and Phosphoric Acids”Inorg. Chem. 1988, 27, 2887-2893
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R. O. Day, J. M. Holmes, S. Shafiezad, V. Chandrasekhar, R. R. Holmes.“Distortion Coordinate for Five Coordinated Tin. A Model for Nucleophilic Substitution. Synthesis and Structures of Hypervalent Anionic Cyanoethylene Dithiolato Stannates.”J. Am. Chem. Soc. 1988, 110, 5377-5383
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V. Chandrasekhar, N. S. Reddy“Reactions of Hexachlorocyclotriphosphazene with 1,2 - Diaminopropane.”Heteerocycles 1989, 28(2), 611-614
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V. Chandrasekhar, T. Chivers, J. Fait, S. S. Kumaravel“Synthesis and Structure of Novel Azo Dyes with Short Intramolecular Se-N Contacts.”J. Am. Chem. Soc. 1990, 112, 5374-5375.
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K. C. Kumaraswamy, V. Chandrasekhar, J. J. Harland, J. M. Holmes, R. O. Day, R. R. Holmes“Pentacoordinate Acyclic and Cyclic Anionic Oxysilicates - A 29Si NMR and X-ray Structural Study”J. Am. Chem. Soc. 1990, 112, 2341-2348
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V.Chandrasekhar, M.G.Muralidhara“Molecular assemblies of organooxotin clusters”Current Science. 1991, 60, 158-165 (invited article)
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M. G. Muralidhara , V. Chandrasekhar“Reactions of Tri-n-butyl and Di-n-butyltin Oxides with Carboxylic acids-Formation of Chain and Ladder Organotin Carboxylates”Ind. J. Chem. 1991, 30A, 487-492
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I. I. Selvaraj, V. Chandrasekhar, T. K. Chandrasekhar, N. S. Reddy.“Cyclophosphazene Linked Tetraphenyl Porphyrins”Heterocycles 1991, 32, 703-710
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R. P. S. Pandian, T. K. Chandrashekar, V. Chandrasekhar“Non-metal Porphyrins: Reactions of PCl3, POCl3 and PhPOCl2 with Tetraphenyl Porphyrin-Spectroscopic and Electrochemical studies”Ind. J. Chem. 1991, 30A, 579-583
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V. Chandrasekhar, M. G. Muralidhara, I. I. Selvaraj.“Reactions of Difunctional Reagents with Chlorocyclophosphazenes.”Heterocycles. 1990, 31, 2231-2266
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I. I. Selvaraj, V. Chandrasekhar“Organic Polymers with Cyclophosphazene Pendant Groups”Polymer Science (Ed. S.Sivaram, Tata McGraw Hill, 1990. 1, 60-64
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V. Chandrasekhar, T. Chivers, S. S. Kumaravel, M. Meetsma, J. C. Van de Grampel.“Preparation of 1,1,5,5-Tetraphenyl,3,7-diaryl,1,5-diphosphatetraazocines and 1,1,3,3,5-Pentaphenyldiphosphatriazine and X-ray Structure of 1,5-Ph4P2N4C2(C6H4CH3-4)2”Inorg. Chem. 1991, 30, 3402-3407
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V. Chandrasekhar, T. Chivers, S. S. Kumaravel, M. Parvez, M. N. Sudheendhra Rao.“Reactions of N,N,N-Tris(trimethylsilyl)benzamidine with Organochalcogen Halides: The Formation of Diazenes via the Resonance Stabilized Radical PhCN2(EPh2) and the X-ray Structures of PhCN2(SCCl3)3 and trans-MeSeN(Ph)CN=NC(Ph)SeMe.”Inorg. Chem. 1991, 30, 4125-4130
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V. Chandrasekhar, M. G. Muralidhara , N. S. Reddy“Reactions of Hexachlorocyclotriphosphazatriene with N-Methyl-1,3-diaminopropane: Isolation of Spirocyclic and not Intermolecular Bridged Products”Heterocycles. 1992, 33, 111-115
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V. Chandrasekhar, M. G. Muralidhara, K. R. Justin Thomas, E. R. T.Tiekink“Isolation and X-ray Crystal Structure of Ph3SnO2SePh; The First Example of an Organotin Ester of Phenyl Seleninic Acid”Inorg. Chem. 1992, 31, 4707-4708
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I. I. Selvaraj, P. Manoravi , V. Chandrasekhar.“Synthesis and Conductivity Studies of Poly(methoxy ethoxy ethyl)-methacrylate. LiCF3SO3”In Solid State Ionics: Material and Applications:Eds.B. V. R. Chowdari, S. Chandra, S. Singh, P. C. Srivastava.(World Scientific, Singapore) 1992, 591-597
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V. Chandrasekhar, T. Chivers, M. Parvez“Structure of 2,2,4,4,6-Pentaphenyl-2,4,1,3,5-diphosphatriazine- A 6-Membered P2N3C ring”Acta Cryst. Sect C . 1993, 49: 393-394
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P. Manoravi, I. I. Selvaraj, V. Chandrasekhar, K. Shahi“Conductivity Studies of New Polymer Electrolytes Based on Polyethyleneglycol(PEG)-sodium iodide System”Polymer. 1993, 34, 1339-1341
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V. Chandrasekhar, K. R. Justin Thomas“Coordination and Organometallic Chemistry of Cyclophosphazenes.”Appl. Organomet. Chem. 1993, 7, 1-31
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K. R. Justin Thomas, V. Chandrasekhar, Parthasarathy Pal, S. R. Scott, R. Hallford, A. W. Cordes“Unusual Tridentate N3 Capping Coordination Behaviour of Hexakis(3,5-dimethyl-pyrazolyl)-cyclotriphosphazene, N3P3(3,5-Me2Pz)6: Synthesis, Spectroscopy and Electrochemistry of Mono- and Dinuclear Copper(II) Complexes and the X-ray structure of N3P3(3,5-Me2Pz)6.CuCl2 ”Inorg. Chem. 1993, 32, 606-611
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V. Chandrasekhar, K. R. Justin Thomas“Recent Aspects in the Structure and Reactivity of Cyclophosphazenes”Structure and Bonding 1993, 81, 41-113
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I. I. Selvaraj, S. Chacklanobis, V. Chandrasekhar“Short Side Chain Poly(oligo oxy ethylene) Acrylates as Polymer Electrolytes: Synthesis and Ionic Conductivity of Poly(methoxy ethoxy ethyl)methacrylate. LiClO4”J .Polym. Sci. Poly. Chem. 1993, 31, 2643-2646
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M. G. Muralidhara, N. Grover, V. Chandrasekhar“Reaction of 1,3-Butanediol with Hexachlorocyclotriphosphazenes: Unusal Non-equivalence of Phosphorus Nuclei in the Spirocyclic Product, N3P3Cl4[OCH(Me)CH2CH2O]”Polyhedron 1993, 12, 1509-1513
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K. R. Justin Thomas, V. Chandrasekhar, S. R. Scott, R. Hallford, A. W. Cordes“Synthesis and Spectroscopy of Mono- and Dinuclear Copper Complexes of a Pyrazolyl Cyclotriphosphazene. Crystal Structure of an Unusual Cyclotriphosphazene Bridged Dicopper complex”J. Chem. Soc. Dalton Trans. 1993, 2589-2594
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1981-87
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Chandrasekhar, V.; Krishnamurthy, S. S.; Vasudeva Murthy, A. R.; Shaw, R. A.; Woods. M.“Spirocyclic Compounds Derived from the Reactions of N3P3Cl6 and N4P4Cl8 with Difunctional Reagents.”Inorg. Nucl. Chem. Lett. 1981, 17, 181-185.
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Chandrasekhar, V.; Krishnamurthy, S. S.; Woods, M.“Metal Complexes of Aminocyclophosphazenes.”ACS Symp. Series, Phosphorus. 1981, 171, 481-485.
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Chandrasekhar, V.; Krishnamurthy, S. S.; Manohar, H.; Vasudeva Murthy, A.R.; Shaw, R. A.; Woods, M.“Reactions of Hexachlorocyclotriphosphazatriene with N-Methyl Ethanolamine: X-ray Crystal Structure of a Dispirocyclotriphosphazatriene, N3P3[NMeCH2CH2O]2Cl2.”J. Chem. Soc. Dalton Trans. 1984, 621-625.
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Suresh, B. S.; Chandrasekhar, V.; Padma, D. K.“Adducts of Silicon tetrafluoride with Aminocyclophosphazenes: Synthesis and Characterization.”J. Chem. Soc. Dalton Trans. 1984, 1787-1790.
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Swisher, R. G.; Vollano, J. F.; Chandrasekhar, V.; Day, R. O.; Holmes, R. R.“Pentacoordinated Structures of Triphenyltin Esters of Anthranilic Acid and p-Aminobenzoic Acid Formed by Intramolecular Carboxylate Group Coordination.”Inorg. Chem. 1984, 23, 3147-3152.
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Vollano, J. F.; R. O. Day, D. N. Rau, V. Chandrasekhar, R. R. Holmes.“Intramolecularly Formed Pentacoordinated Structures of Triphenyltin Esters of Salicylic Acid, o-Anisic Acid and p-Methylthiobenzoic Acid.”Inorg. Chem. 1984, 23, 3153-3160.
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V. Chandrasekhar, S. Karthikeyan, S. S. Krishnamurthy, M. Woods. “Some Reactions of Octachlorocyclotetraphosphazene with Aliphatic Difunctional Reagents.”Ind. J. Chem. 1985, 24a, 379-383.
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V.Chandrasekhar, R.O.Day, R.R.Holmes“A new structural form of tin octahedrally coordinated in a drum shaped molecule.”Inorg. Chem. 1985, 24, 1970-1971
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R. R. Holmes, R. O. Day, V.Chandrasekhar, J. M. Holmes“Synthesis and Molecular Structure of Five coordinated Spirocyclic Anionic Silicates Containing t-Butyl Groups. Hydrogen Bonding Effects”Inorg. Chem. 1985, 24, 2009-2015.
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R. R. Holmes, R. O. Day, V. Chandrasekhar, J. J. Harland, J. M. Holmes“Acyclic Substituent Effects on the Molecular Structure of Cyclic Containing Five Coordinated Anionic Silicates. A Model for Nucleophilic Substitution at Silicon”Inorg. Chem. 1985, 24, 2016-2020
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R. R. Holmes, R. O. Day, V. Chandrasekhar, S. Shafiezad, J. J. Harland, D. N. Rau, J. M. Holmes“New Ring Systems of Elements of Main Groups IV and V”Phosphorus and Sulphur.1986,28,91-98
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R. R. Holmes, R. O. Day, V. Chandrasekhar, J. F. Vollano, J. M. Holmes“Discrete, Dimeric and Polymeric Structures of Triphenyltin Esters of Chlorobenzoic Acids”Inorg. Chem. 1986, 25, 2490-2494
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P. J. Smith, R. O. Day, V. Chandrasekhar, J. M. Holmes, R. R. Holmes“Chain Structures of Trimethyltin Esters of Salicylic Acid and o-Anisic Acid: Tin-119 Mössbauer Study of a Series of Trimethyltin Carboxylates”Inorg. Chem. 1986, 25, 2495-2499
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R. O. Day, J. M. Holmes, V. Chandrasekhar, R. R. Holmes“A New Structural Form of Tin in an Oxygen Capped Cluster”J. Am. Chem. Soc. 1987, 109, 940-941
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R. R. Holmes, C. G. Schmid, V. Chandrasekhar, R. O. Day, J. M. Holmes.“Oxo Carboxylate Tin Ladder Clusters. A New Structural Class of Organotin Compounds”J. Am. Chem. Soc. 1987, 109, 1408-1414
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V. Chandrasekhar, C. G. Schmid, S. D. Burton, J. M. Holmes, R.O. Day, R. R. Holmes“New Drum and Ladder OrganooxotinCarboxylates”Inorg. Chem. 1987, 26, 1050-1056
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R. R. Holmes, R. O. Day, V. Chandrasekhar, J. M. Holmes“Formation and Structure of Cyclic Five Coordinated Antimony Derivatives. The First Square Pyramidal Geometry for a Bicyclic Stiborane”Inorg. Chem. 1987, 26, 157-163
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R. R. Holmes, R. O. Day, V. Chandrasekhar, J. M. Holmes“Distortion Coordinate for Non-rigid Five Coordinated Antimony. Synthesis and Structure of Oxygen and Sulphur Containing Cyclic Organo Stiboranes”Inorg. Chem. 1987, 26, 163-168
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R. R. Holmes,V. Chandrasekhar, R. O. Day, J. J. Harland, J. S. Payne“Sterically Hindered Pentacoordinated Phosphorus and Silicon Compounds”Phosporus Sulfur Silicon and Related Elements.1987, 30(1-2), 409-412